Dimock Well Water HW-9 Acetone, Arsenic, Barium, Copper, Lead, Lithium, ethane, methane, glycols Pennsylvania

Comment

1. Without predrilling data, it is not possible to comment on the cause for any water quality problems.

2. Where possible, I have noted situations where elevated levels of a water quality parameter exists in Pennsylvania.

3. If duplicate analysis provided, I attempted to use the highest reported value.

4. New Document - http://water.epa.gov/action/advisories/drinking/upload/dwstandards2011.pdf

5. This is not about cause and effect; it is about a review of the data.

6. A Well by Well - Review of the Data for Dimock, PA collected by EPA

Well – HW-9 (2/3/2012)

With the exception of the following parameters, the remaining values were reported as NOT Detected (U)

Anionic Surfactants – < 0.01 mg/L – the secondary drinking water standard for foaming agents is 0.5 mg/L.  (OK)

http://www.chemetrics.com/products/pdf/detergents.pdf

Arsenic – 0.001 mg/L – drinking water standard is <  0.010 mg/L – this does not suggest any specific impact and arsenic is a common problem in NEPA – about 6 % of private wells have arsenic above 0.010 mg/L. 

http://www.water-research.net/arsenic.htm

Barium – 0.106 mg/L – the primary drinking water standard for barium is 2.0 mg/L –– this does not suggest any specific impact and barium is typically detectable in non-saline impacted water at a level of less than 1 mg/L. (OK)

Boron –< 0.050 mg/L (Total) – no specific drinking water standard drinking water standard is available. EPA appears to have a long-term health advisory of 2.0 mg/L, but other states have limits that range from 0.6 to 1 mg/L.   Therefore, this does not appear to suggest any form of impact.  (OK)

Source: http://www.epa.gov/ogwdw/ccl/pdfs/reg_determine2/healthadvisory_ccl2-reg2_boron_summary.pdf

http://www.who.int/water_sanitation_health/dwq/boron.pdf

Calcium- 23.4 mg/L (Total)– no specific drinking water standard drinking water standard is available.  (OK) – the value seems low.

Chloride –13.8 mg/L (OK) – drinking water standard is <  250 mg/L – this does not suggest any specific impact.

Chromium- < 0.002 mg/L (D) and the EPA/ PADEP primary drinking water standard is < 0.100 mg/L (OK).

Copper – 0.00375 mg/L (OK)- the secondary drinking water standard is 1.0 mg/L and the primary drinking water standard is 1.3 mg/L. (OK)

Ethane – < 0.0012 mg/L  – No specific drinking water standard (OK)

Fluoride – < 0.1 mg/L (OK) – drinking water standard is < 2 mg/L- PADEP drinking water standard is 2 mg/L.

Iron – < 0.100 mg/L (Total)) – Iron is regulated as a secondary drinking water standard in Pennsylvania and the action limit is 0.3 mg/L.  Therefore, the total iron content does not exceed the secondary drinking water standard.  (OK)

Lead – 0.0016 mg/L (Total) - Lead is regulated as a primary standard (EPA and PA) at 0.015 mg/L, but the action level in PA for source water is 0.005 mg/L. Because of the hits for copper and lead, it is possible that the nuisance bacteria may be causing some corrosion related problems  (MIC) and it may be worth conducting a first flush analysis of the water. MIC – Microbiologically Induced Corrosion – Problem recommend inspection of the well, camera survey, shock disinfection, and retesting.  This is a common problem in NEPA.  (OK) = Level below all action limits, but monitoring recommended.

Lithium – < 0.200 mg/L (Total) – no specific drinking water standard drinking water standard is available, but EPA has recommend a level be below 0.7 mg/L    (OK)

http://www.water-research.net/Waterlibrary/privatewell/lithium.pdf

Methane –  0.0043 mg/L (J-actually below the detection limit for the method)  – No specific drinking water standard. (OK). The well water  is not above the new action limit of 7 mg/L. For more details, go to http://www.water-research.net/methanegas.htm

Magnesium-4.00 mg/L– no specific drinking water standard drinking water standard is available.  (OK)

Manganese– 0.0013 mg/L (Total) – Manganese is regulated as a secondary drinking water standard in Pennsylvania and the action limit is 0.05 mg/L.  Therefore, the total manganese content does NOT exceed the secondary drinking water standard.   (OK)

Nickel – 0.0014 mg/L  – no specific drinking water standard drinking water standard

is available, but the EPA has suggest a MCL of 0.1 mg/L.   (OK)

http://www.epa.gov/ogwdw/pdfs/factsheets/ioc/tech/nickel.pdf

Sodium –8.48  mg/L  (D) – no specific drinking water standard drinking water standard is available, but the EPA has added it to the Candidate List to provide more analysis.  The EPA’s initial value of 20 mg/L has been clearly identified as not realistic.  When chloride (salt is sodium chloride) is present at a concentration of over 250 mg/L, the water can have an “off” taste. At 400+ mg/L chloride, the water will taste definitely salty. (Source- Dr. Brian Redmond, Professional Geologist). (OK)

Sulfate –18. 7 mg/L (OK) – drinking water standard is <  250 mg/L – this does not suggest any specific impact.

Strontium – < 0.200 mg/L   – no specific drinking water standard drinking water standard is available, but it is on the EPA Candidate List.  The EPA recommends that drinking water levels of nonradioactive strontium should not be more than 4 mg/L.  The report limit is consistent with background levels in Northeastern Pennsylvania.  If the background level was above 4 mg/L, it would be advisable to test for radiological parameters, especially alpha/beta.  (OK)

Total Dissolved Solids  – 110 mg/L   – Total Dissolved Solids is regulated as a secondary drinking water standard by the PADEP in Pennsylvania and the action limit is 500 mg/L. 

Total Suspended Solids - < 10 mg/L – no standard, but would recommend retesting to obtain a lower detection limit.

Uranium –0.0021 mg/L (Total) – Uranium is regulated as a primary drinking water standard by the EPA and PADEP in Pennsylvania and the action limit is 0.030 mg/L.  (OK)

Zinc  –0.0206 mg/L – Zinc is regulated as a secondary drinking water standard by the PADEP in Pennsylvania and the action limit is 5.0 mg/L.  (OK)

Nitrate+Nitrite- N – 2.41 mg/L, this is well below the EPA / PADEP drinking water limit of 10mg N/L for nitrate-N and would also be below the limit of 1.0 mg N/L for nitrite-N. (OK)

Acetone - the reported value was 0.0031 mg/L (J- actually below the actual water limit of  < 0.002 mg/L) and no trigger limit is reported, but PADEP has a Medium Specific Concentration (MSC) for aquifers with a TDS of < 2500 mg/L of 33.0 mg/L and Massachusetts appears to have a drinking water standard of 6.3 mg/L. (OK)

http://www.mass.gov/dep/water/drinking/standards/acetone.htm

Ethylene glycol –  the reported value is < 10 mg/L – there is not standard, but the EPA has a guidance limit of < 7 mg/L.  Other states have lower and higher standards:

New Jersey 0.300 mg/L (300 ppb)

Arizona 5.5 mg/L (5500 ppb)

New Hampshire 7.0 mg/L (7000 ppb)

Florida, Massachusetts, and Minnesota14.0 mg/L (14,000 ppb)

Minnesota

At a minimum, I would recommend retesting for ethylene glycol other and glycol-type compounds using a method that is more sensitive or conducting some type of standard additions analysis.

1. No major problems

2. Recommend additional testing for nitrite.

3. Arsenic was detected.

4. Copper, lead, and zinc detected this could suggest a corrosion related problem. This is a common problem in NEPA

Document can not be copied in whole or part without the expressed written permission of Mr. Brian Oram, B.F. Environmental Consultants Inc. http://www.bfenvironmental.com

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