Showing posts with label heterotrophic bacteria. Show all posts
Showing posts with label heterotrophic bacteria. Show all posts

Thursday, August 30, 2012

Marcellus Shale Coalition Pre-Drilling Water Sampling



Pittsburgh, Pa. – Today, the Marcellus Shale Coalition (MSC) released a Recommended Practice (RP) for pre-drill water supply surveys. This is the third in a series of recommended practices, all aimed at reinforcing the MSC’s Guiding Principles to “continuously improve our practices and seek transparency in our operations” while furthering a fact-based dialogue that encourages responsible American natural gas development.
Pennsylvania regulations require natural gas producers to sample and test – with the owner’s consent – all water supplies within 2,500 feet of a proposed Marcellus Shale natural gas well. These pre-drill tests, which are conducted by certified laboratories, provide a baseline analysis of water chemistry prior to site preparation and development activities. Many natural gas producers test well beyond the 2,500 feet requirement, and were doing so prior to Pennsylvania enacting these new regulations.

According to the Center for Rural Pennsylvania, nearly 40 percent of Pennsylvania’s water wells do not meet at least one safe drinking water standard and another 20 percent of wells contain pre-existing methane.
“For years, well before shale gas production began in the Commonwealth, straightforward science has informed us that Pennsylvania’s groundwater chemistry drastically varies across regions,” said MSC president Kathryn Klaber. “This Recommended Practice builds upon what’s required by law and lays out in great detail steps operators can take to help ensure homeowners have a clear understanding of their water quality before natural gas-related activities begin. These tests, paid for by the natural gas producer, are shared with the well owners and state regulators, serving a critical public health function in many cases.”

Developed by technical experts from a host of MSC member companies, this RP recommends the following steps:
  • A pre-drill survey should be conducted on all identified water supplies within a given area of the well pad surface location as required by the State Regulatory Agency (SRA).
     
  • Water supply sources such as wells, springs and ponds should be evaluated prior to earth disturbance for site construction or prior to spud. Consideration should also be given to sampling water supply sources that are not currently in use.
     
  • With the assistance of the water supply owner, locate the water supply(ies) and sampling location(s). Use GPS (preferably NAD83 datum) to determine and record the latitude and longitude of each water supply.
     
  • The samples shall be collected, in accordance with all appropriate sample collection, preservation, handling, and defensible chain-of-custody procedures. Appropriate sample collection procedures can be found on the United States Environmental Protection Agency (USEPA) website (www.epa.gov).
     
  • Water samples shall be analyzed by an SRA certified laboratory using USEPA SW-846 methods or drinking water methods (where drinking water methods exist). For parameters that have a Maximum Contaminant Level (MCL), the laboratory should be instructed to provide a laboratory reporting limit no greater than the published MCL.
     
  • Operators should inform the water supply owners and/or residents that any and all information/data collected will be provided to the owner/occupant and to the SRA (if required by state regulations) and, as such, the information could be disclosed as public information upon inquiry to the SRA.
Continued Klaber: “Additionally, the MSC is developing a robust pre-drill water quality database. When complete, this first of a kind library will serve as an important environmental and public health tool to help address water quality challenges that have persisted in rural communities for decades.”

The parameters they recommended
Alkalinity 
Total Chromium
Oil & Grease 
Total Arsenic
pH 
Total Barium
Specific Conductance 
Total Lead
Total Dissolved Solids 
Total Selenium
Total Suspended Solids 
Total Strontium
Chloride 
Total Calcium
Sulfate 
Total Iron
Total Hardness 
Total Magnesium
Surfactants (MBAS/foaming agents) 
Total Manganese
Benzene, Toluene, Ethylbenzene, Xylenes (BTEX)
Total Potassium
Dissolved Methane* 
Total Sodium
Dissolved Ethane 
E. Coli
Dissolved Propane 
Total Coliform
Nitrate as N 
Turbidity**

Comments
1. I am glad that a more uniform list is being recommended.
2. I would like to see the full range of VOCs and MTBE.
3. I would like to see glycols added to the list or at least added when the conditions seem correct.
4. I think the Guidance should include more on purging and documenting the water quality during the purging process to make sure the purge was adequate, but it is a good start.
5. During purging, the pH, mv or ORP, Conductivity, and Temperature should be documented.  If possible, this is also a great time to measure turbidity.
6. I strongly recommend adding Total Aluminum to this testing.
7. I strongly recommend adding Bromide to this testing.
8. It would be nice if the guidance provided more information on detection limits, but I do like the fact that want the results reported in a uniform manner. 
9. Would like to see testing for nuisance bacteria or heterotrophic bacteria when the conditions seem appropriate - probably 50% of the time.

B.F. Environmental Consultants Inc. provides training in proper baseline sampling practices, review and use of baseline testing data, and educating professionals to work with private well owners, plus we provide training and educational programs for private well owners.

B.F. Environmental Consultants Inc also does post drilling assessments and reviews.

The actual guidance document can be found here.

Tuesday, April 10, 2012

HW-13 Dimock Data EPA January 30, 2012

Comment

1. Without predrilling data, it is not possible to comment on the cause for any water quality problems.
2. Where possible, I have noted situations where elevated levels of a water quality parameter exists in Pennsylvania.
3. If duplicate analysis provided, I attempted to use the highest reported value.
5. This is not about cause and effect; it is about a review of the data.

Well – HW-13

With the exception of the following parameters, the remaining values were reported as NOT Detected (U)

Anionic Surfactants – < 0.01 mg/L – the secondary drinking water standard for foaming agents is 0.5 mg/L.  (OK)

Heterotrophic Bacteria – 560 cfu/ml -the general guidance for “standard plate count” or total bacterial count is < 500 colonies per ml (OK).  This would suggest a potential bacterial issue and if there are problems with iron, manganese, discolored water, or odor, it is possible that the cause could be related to microbiologically induced corrosion and “nuisance bacteria”.

Ethane 0.024 mg/L  – No specific drinking water standard (OK)

Methane 1.30 mg/L  – No specific drinking water standard. (OK).
The well water is not above the new action limit of 7 mg/L, but the well should be fitted with a basic vented well cap.   For more details, go to http://www.water-research.net/methanegas.htm

There are places in PA were baseline levels of methane gas are at or above 7 mg/L. In general, I would estimate that 1 to 3 % of private wells may have elevated levels of methane.  In addition to modifying the well, it would be advisable to conduct isotopic analysis.  Based on the ratio of methane to ethane, the ratio is 54.  This suggests the gas is of thermogenic origin and isotopic analysis is critical.  No specific health concern – but action needed to properly vent gas. 

Ethylene glycol –  the reported value is < 10 mg/L – there is no standard, but the EPA has a guidance limit of < 7 mg/L.  Other states have lower and higher standards:

New Jersey 0.300 mg/L (300 ppb)
Arizona 5.5 mg/L (5500 ppb)
New Hampshire 7.0 mg/L (7000 ppb)
Florida, Massachusetts, and Minnesota14.0 mg/L (14,000 ppb)
Minnesota

At a minimum, I would recommend retesting for ethylene glycol other other glycol compounds using a method that is more sensitive or conducting some type of standard additions analysis.
Note: I have been to this location and conducted only a field screening test for glycol - the field test is manufactured by Chematics Inc. and the result was not detectable for glycol, i.e., < 1 mg/L. 

Chloride – 8.31 mg/L (OK) – drinking water standard is <  250 mg/L – this does not suggest any specific impact.

Sulfate – 10.6 mg/L (OK) – drinking water standard is <  250 mg/L – this does not suggest any specific impact.

Barium - 0.225 mg/L (Total) and 0.235 mg/L (D) – drinking water standard is <  2 mg/L – this does not suggest any specific impact and barium is typically detectable in non-saline impacted water at a level of less than 1 mg/L. (OK)

Calcium- 31.9 mg/L (Total) and 33.1 mg/L (D) – no specific drinking water standard drinking water standard is available.  (OK)

Iron – 2.87 mg/L (Total) and 0.33 mg/L (D) – Iron is regulated as a secondary drinking water standard in Pennsylvania and the action limit is 0.3 mg/L.  Therefore, the total iron content exceeds the secondary drinking water standard.  Elevated level of iron is a common water quality problem in Northeastern PennsylvaniaAction is Recommended, because of an aesthetic issue.    Check for MIC and Nuisance Bacteria.

Magnesium- 6.62 mg/L (Total) and 6.84 mg/L (D) – no specific drinking water standard drinking water standard is available.  (OK)

Manganese– 0.031 mg/L (Total) and 0.0164 mg/L (D) – Manganese is regulated as a secondary drinking water standard in Pennsylvania and the action limit is 0.05 mg/L.  Therefore, the total manganese content does not exceed the secondary drinking water standard.   (OK)

Nickel - 0.0016 mg/L (Total) and 0.0013 mg/L (D) – – no specific drinking water standard drinking water standard is available, but the EPA has suggest a MCL of 0.1 mg/L.   (OK)

Sodium –12.6 mg/L (Total) and 12.9 mg/L (D) – – no specific drinking water standard drinking water standard is available, but the EPA has added it to the Candidate List to provide more analysis.  The EPA’s initial value of 20 mg/L has been clearly identified as not realistic.  When chloride (salt is sodium chloride) is present at a concentration of over 250 mg/L, the water can have an “off” taste. At 400+ mg/L chloride, the water will taste definitely salty. (Source- Dr. Brian Redmond, Professional Geologist). (OK)

Strontium 0.764 mg/L (Total) and 0.774 mg/L (D)  – no specific drinking water standard drinking water standard is available, but it is on the EPA Candidate List.  The EPA recommends that drinking water levels of nonradioactive strontium should not be more than 4 mg/L.  The report limit is consistent with background levels in Northeastern Pennsylvania.  If the background level was above 4 mg/L, it would be advisable to test for radiological parameters, especially alpha/beta.  (OK)

Toluene – 0.0012 mg/L - Toluene is regulated as a primary drinking water standard by the EPA and PADEP in Pennsylvania and the action limit and maximum contaminant level goal is 1.0 mg/L, but over 0.0040 mg/L toluene can create odor related problems.  (OK)

Uranium 0.0003 mg/L (Total) and 0.0032 mg/L (D)  – Uranium is regulated as a primary drinking water standard by the EPA and PADEP in Pennsylvania and the action limit is 0.030 mg/L.  (OK)

Zinc  0.004  mg/L (Total) and < 0.002 mg/L (D)  – Zinc is regulated as a secondary drinking water standard by the PADEP in Pennsylvania and the action limit is 5.0 mg/L.  (OK)

Total Dissolved Solids  15 mg/L   – Total Dissolved Solids is regulated as a secondary drinking water standard by the PADEP in Pennsylvania and the action limit is 500 mg/L.  (Question – this value seems inaccurate or a typo – This should be redone.)

Nitrate+Nitrite- N – 0.78  mg/L, this is well below the EPA / PADEP drinking water limit of 10mg N/L for nitrate-N and would also be below the limit of 1.0 mg N/L for nitrite-N. (OK)

Total Nitrogen – 1.45 mg/L (No Standard)

No major problems

1. Heterotrophic bacteria data is elevated.

2. Iron is elevated and exceeds a secondary drinking water standard.

3. Methane/Ethane Ratio could suggest the source of the methane is of thermogenic origin and the level of methane is well below the action level of 7 mg/L.
4.Total Dissolved Solids results seem inaccurate or there is a typo in the draft report.

5. Retesting for glycols using a more sensitive technique is recommended.  Note - I have used a field screening test for glycols and the level was less then 1 mg/L - Note- Not a certified or approved method.

6. Toluene detected – but not at a level above a maximum contaminant level or a level that could cause aesthetic issues. 


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Document can not be copied in whole or part without the expressed written permission of Mr. Brian Oram, B.F. Environmental Consultants Inc. http://www.bfenvironmental.com

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